Chlorides leachable level can be as little as 10 ppm, even though chlorides are contained within insulation materials. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. Selection of stainless steels for handling chlorine. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Effect of chloride deposition on stress corrosion cracking of 316l. This paper aims to explore the corrosion resistance of some stainless steels in.
Effect of chloride deposition on stress corrosion cracking. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. These steels can be heat treated to high strength levels. Guidelines for using stainless steel in the water and. Chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Together, chlorine and chloride cause stainless steel failures that wouldnt occur by exposure to chlorine or chloride alone. Oct 21, 2019 chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Temperature and corrosion rate more complex than you think. The investigation of austenitic stainless steel attacked by acid chloride containing environment was done.
The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. External applied stress by ubending was also applied to specimen in order to further study stress corrosion cracking phenomenon. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. Introduction stainless steel is often perceived as the backbone of modern industry 1. I am specifying pipes for a water system with 500 ppm chloride in solution.
The passive layer on stainless steel can be attacked by certain chemical species. Copper heaters will react with the salt water and turn the pool green. Behaviour of stress corrosion cracking of austenitic. Does anyone know if theres a generally safe level of chlorides in water that shouldnt cause corrosion in metals. This makes it insufficient for purposes in which excess amounts of chloride are present. Austenitic stainless steel ss type aisi 316l is being used to manufacture waste containers for radioactive intermediate level waste ilw in the uk. Stainless steel, due to its superior corrosion resistance relative to most other metals, such as carbon steel and aluminum, becomes the cathode, accelerating the corrosion of the anodic metal. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Chloride stress corrosion cracking and 316 stainless steel. The influence of chloride content, ph and temperature of test solution on the. What is the minimum concentration of chloride ion required. Stainless steel grades 600 series this series of stainless steels grade is commonly referred to as precipitation hardening stainless steels.
Temperature and corrosion rate more complex than you. Stress corrosion cracking international institute of. Salt water pools are high in free chlorides, which will cause chloride stress corrosion cracking in stainless steel heaters. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl.
It requires a susceptible material and, depending on the material, sufficient levels of. Reference is often made to stainless steel in the singular sense as if it were one material. Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against. Stress corrosion cracking in duplex stainless steel. Chloride ion is the most common of these and is found in everyday materials such as salt and bleach. In addition to chloride ion, can be caused by elevated temperatures for extended. Higher levels of chloride might cause crevice corrosion and pitting. So instead of the typical schedule 40 pipe, could i. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. Corrosion protection coatings are beneficial for thermally. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Two main types of stainless steel corrosion are of particular concern in water system applicationscrevice corrosion. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. A novel accelerated test for chloride stress corrosion cracking designed for austenitic stainless steel is presented.
Harsh pitting corrosion is a localized damage that eats pits into stainless steel. Although no stainless steel grade is totally immune. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. The 304 austenitic stainless steel was experimented in acid hydrogen chloride aqueous solution with mixing ratio 1. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. The steel was manufactured before 1970 with possible higher levels of. Chlorine in contact with water and as a dissolved gas, sometimes found in water treatment applications, is potentially aggressive to stainless steels. On the stress corrosion cracking of lean duplex steel in. Chloride level in carbon steel pipes corrosion engineering.
Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Stress corrosion cracking, austenitic stainless steels, sodium chloride 1. Effects of deicing agents magnesium chloride and sodium. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Stress corrosion cracking of an austenitic stainless steel in. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. That is, cracks initiate and propagate at a slow rate for example, 10 to 10 ms until the stresses in the remaining ligament of metal ex ceed the fracture strength. Selection of stainless steels for handling chlorine cl2. As mentioned previously, stainless steels protective film is less effective when the oxide surface layer becomes damaged or scratched, which can cause corrosion in those areas. Key word environment, winter maintenance, deicing, magnesium chloride, sodium chloride, corrosion 18. Presumably, the corrosion products of both ductile iron and carbon steel were influenced by the level of chloride concentrations, which in turn reflected the variations in corrosion reactions. Chloridechlorine levels and stainless steel alloy selection. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Monitoring of chloride stress corrosion cracking of. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. For this reason, stainless steels are being used in increasingly corrosive brine environments. Higher temperatures reduce the permissible chloride level. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e.
There is a synergistic relationship between dissolved oxygen and the chloride level. To take another example of chloride scc of austenitic stainless steels, tube and shell heat exchangers are frequently constructed using stainless steel tubes since these must be thinwalled and corrosion cannot be tolerated with carbon steel tube plates and shell since these can be made much thicker to provide a corrosion allowance. Chloride stress corrosion cracking clscc is one the most common reasons why. Behaviour of stress corrosion cracking of austenitic stainless. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. They are subject to crevice corrosion and pitting in chloride containing environments and are also. What forms of corrosion can occur in stainless steels. The effect of salt loading on chlorideinduced stress. Clscc chloride stress corrosion cracking mechanism china. It is especially important to avoid any mechanical tensile stress concentration. The stainless will be ok at this level of salinity if at room temperature and neutral ph, but be cognizant of the risks to the carbon steel of galvanic corrosion and the buildup of fe concentrations, which are deleterious to stainless. Duplex stainless steel having attractive combination of austenitic and ferritic properties is being used in industry such as petrochemical, pulp and paper mills.
It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Effect of ph and chloride contents on stress corrosion. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Chloride corrosion of carbon steel pipe engineering stack. The resistance of austenitic stainless steels to scc is related to the nickel. Now, stainless steel can be treated so that it lasts longer and experiences less trauma. Design guidelines for the selection and use of stainless steel nidl distributed by. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Stress corrosion cracking scc is a common issue with many specialty alloys. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Chloride cracking of 300 series stainless steels continues to occur in a number.
Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316. Corrosion of stainless steel in sodium chloride brine. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Elevated stress susceptible material corrosive environment surface contamination by atmospheric chlorides sufficient humidity epri has a multiyear project to. Stress corrosion cracking of sensitized type 304 stainless. I know ive seen here and elsewhere that below 200250ppm sulphates is generally safe for stainless steel, but ive not seen anything related to chlorides. Stress corrosion cracking the international institute of.
While its tensile strength is not at the level of austenitic stainless steel, ferritic stainless steel is. Environmental factors play an important role in how quickly corrosion develops as. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. This mode of attack is termed stress corrosion cracking scc. Chloride stress corrosion cracking in austenitic stainless. Susceptibility assessment criteria for chlorideinduced.
The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. As temperature increases, and as long as the passive film remains intact, corrosion rate does not increase. Pitting corrosion and stress corrosion cracking of. Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by. What is the maximum chloride in ppm that can be allowed in. Ordinarily we would specify 316l stainless steel to limit the corrosion, but i was asked if we could instead specify carbon steel pipe with a corrosion allowance. So instead of the typical schedule 40 pipe, could i realistically use schedule 80 or 120 etc. Three general classifications are used to identify stainless steels. Corrosion of unprotected carbon steel occurs even inside reinforced. Pitting corrosion is a localized form of corrosion by which cavities or holes are produced in the material. However, the susceptibility of austenitic stainless steel to scc in a warm and oxygenated environment at certain chloride levels limits their use in many. Im particularly interested in stainless steel, being my boiler is that material not sure what type of stainless steel.
With chloride containing environments and stainless steel, there is usually a threshold. The combination of tensile stress and a specific corrosive environment can crack stainless steels. To evaluate chlorideinduced stress corrosion cracking of type 304 stainless steel, corrosion 2012, march 1115, 2012, salt lake city, ut, agencywide documents access and management system adams accession no. But once the passive film is overwhelmed by the increase in temperature, corrosion rate increases rapidly. In this study, the corrosion and stress corrosion behavior of duplex stainless steel in 3. Stress corrosion cracking scc of austenitic stainless steels of types 316 was. Cscc can attack highly resistant austenitic stainless steel. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Because mild steel was not included in this research study, further implementation of findings from this report will be delayed until an additional study on the conosive effects of magnesium chloride on mild steel is completed.
Stainless steels are corrosionresistant, but to take full. They are subject to crevice corrosion and pitting in chloride containing environments and are also subject to stress corrosion cracking and hydrogen embr ittlement. Stresscorrosion cracking is a delayed failure process. The test material 316l stainless steel was received in rolled plate. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Effect of chloride deposition on stress corrosion cracking of. The sequence of events involved in the scc process is usually divided into three stages. Chloride stress corrosion cracking in austenitic stainless steel. Stainless steel bellows which typically have high stress levels come in contact. High performance stainless steels nickel institute. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. However, when introduced to chlorides, it tends to suffer stress corrosion cracking fairly quickly.
Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking facts and how to reduce the risk. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Jul 31, 2017 presumably, the corrosion products of both ductile iron and carbon steel were influenced by the level of chloride concentrations, which in turn reflected the variations in corrosion reactions. The risk for corrosion in brines is associated with the chloride content, temperature, ph and oxygen level. Feb 28, 2018 however, when introduced to chlorides, it tends to suffer stress corrosion cracking fairly quickly. Stress corrosion cracking in duplex stainless steel great. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. Chloride stress corrosion cracking inspectioneering. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Boilersafe level of chlorides and other compounds in water. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of.